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Lithium iron phosphate battery
in the WAYU GIB PMVR.467154.080 navigation buoy
Material safety data sheet (MSDS)
  Version 1
18.11.2024

Lithium iron phosphate battery
in the WAYU GIB PMVR.467154.080 navigation buoy

Material safety data sheet (MSDS)

1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY OR SUPPLIER

   
Trade name Battery of the WAYU GIB PMVR.467154.080 navigation buoy
Article number  
Registration number (REACH) This information is not available
EC number not applicable
CAS number not applicable

Relevant identified uses of the substance or mixture and uses advised against

   
Identified uses: Intended to power portable equipment with 12 V DC.

Details of the supplier of the safety data sheet

 
UCNL LLC
Registered address: 121205, Moscow, Skolkovo Innovation Center territory, Bolshoy Blvd., house 42, building 1, apartment: FLOOR 3, PREMISES 1098, WORKSTATION 10
   
Telephone: 8(499)3222537
Fax:  
E-mail: hello@unavlab.com
Website: unavlab.com
Emergency telephone number 03 emergency medical service
01 fire service
Emergency information service 8(499)3222537

2. HAZARD(S) IDENTIFICATION

2.1. Classification of the substance or mixture

Classification in accordance with Regulation (EC) No. 1272/2008 (CLP) In accordance with Article 3 (3) of REACH, this product (these products) is (are) an article (articles). Articles are not subject to the mandatory labeling required by laws on hazardous substances. This product is not classified as hazardous to health or the environment under the Regulation on the classification, labeling and packaging of substances and mixtures (CLP).

Remarks

For the full text of hazard statements and EU hazard statements, see SECTION 16.

2.2. Label elements

Labeling in accordance with Regulation (EC) No. 1272/2008 (CLP)
Signal word Not applicable
Hazard statements

not applicable  
   

Precautionary statements
Precautionary statements - response: not applicable

2.3. Other hazards

The battery’s constituent substances are contained in hermetically sealed cells designed to withstand the temperatures and pressures encountered under normal operating conditions. This design also provides protection against ignition or explosion during normal operation and prevents leakage of these substances. If the battery housing is destroyed, the constituent substances are released.

3. COMPOSITION (INFORMATION ON INGREDIENTS)

3.1. Substances

Lithium  
EC number 231-102-5
CAS number 7439-93-2
Iron phosphate  
EC number 233-149-7
CAS number 10045-86-0

4. FIRST-AID MEASURES

4.1. Description of first-aid measures

If inhaled
Provide fresh air or oxygen and call a physician.
In case of skin contact
Not expected.
In case of eye contact
Not expected.
If swallowed
Not expected.

4.2. Most important symptoms and effects, both acute and delayed

No symptoms or effects are known to date.

4.3. Indication of any immediate medical attention and special treatment needed

Not applicable

5. FIRE AND EXPLOSION SAFETY MEASURES AND EQUIPMENT

5.1. Extinguishing media

Suitable extinguishing media
CO2, dry powder extinguishing agent or fine water spray. Fight large fires with fine water spray or alcohol-resistant foam.
Unsuitable extinguishing media None

5.2. Special hazards arising from the substance or mixture

Toxic gases may form when heated or in the event of a fire.
Hazardous combustion products
In the event of a fire, toxic gases may form.

5.3. Advice for firefighters

Fight the fire from an adequate distance, observing the usual precautions.
Wear self-contained breathing apparatus.

6. MEASURES TO PREVENT AND ELIMINATE ACCIDENTS AND EMERGENCIES AND THEIR CONSEQUENCES

6.1. Personal precautions, protective equipment and emergency procedures

For non-emergency personnel Wear suitable protective equipment (including the personal protective equipment specified in section 8 of the safety data sheet) to prevent any contamination of the skin, eyes and personal clothing. Do not breathe dust. Avoid contact with skin, eyes and clothing.

6.2. Environmental precautions

Do not allow the material to enter the ground / soil.

6.3. Methods and material for containment and cleaning up

Advice on preventing leakage
Not required Advice on cleaning up a leak
Collect mechanically.
Other information relating to spills and releases
Place in suitable containers for disposal.
Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13.

7. RULES FOR STORAGE AND HANDLING OF THE CHEMICAL PRODUCT DURING LOADING AND UNLOADING

7.1. Precautions for safe handling

Do not allow the battery cells to become saturated with water (seawater).
Do not expose to strong oxidizers.
Do not throw. Avoid mechanical (impact) loads.
Do not disassemble, modify the design or deform.
Do not allow the positive and negative terminals to come into contact with electrically conductive material.
Use only the specified chargers and tools for recharging and discharging.
Advice on industrial hygiene Wash hands before breaks and after work. Keep away from food, drinks and animal feed.

7.2. Conditions for safe storage, including any incompatibilities

Avoid exposure to direct sunlight, high temperatures and high humidity. Store in a cool place. Storage temperature: -20 to 60 °C. Permissible air humidity: 45–85 %. Incompatible substances or mixtures
Store separately from water.
Do not store together with electrically conductive materials.
Other advice to consider Do not store in places subject to static electricity buildup.
Protect from heat and direct sunlight.
Protect from air humidity and water.

7.3. Specific end use(s)

Use only for the intended purpose; see the user’s manual.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

8.1. Engineering controls:

Do not store batteries near sources of heat or open flames. Store in a dry, cold place.

8.2. Personal protective equipment:

Respirator: Not required during normal operation. In the event of a fire, self-contained breathing apparatus (SCBA) is required. Eye/face protection: Not required if safety rules are followed.
Gloves: Not required when handling batteries.
Foot protection: Not required

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance

   
Physical state solid
Odor odorless
Odor threshold no data available

Other physical and chemical parameters

   
pH (value) not applicable
Density at 20 °C not applicable
Melting point/freezing point no data available
Initial boiling point and boiling range no data available
Flash point (closed cup) not applicable
Evaporation rate no data available
Flammability (solid, gas) not applicable
Explosive limits  
• lower explosive limit (LEL) no data available
• upper explosive limit (UEL) no data available
Explosive limits of dust clouds no data available
Vapor pressure no data available
Vapor density no data available
Bulk density no data available
Relative density no data available
Solubility(ies)  
Solubility in water not applicable
Partition coefficient  
n-octanol/water (log KOW) no data available
Ignition temperature no data available
Auto-ignition temperature no data available
Decomposition temperature no data available
Viscosity no data available
Explosion hazard no data available
Oxidizing properties no data available

9.2. Other information

No additional information

10. STABILITY AND REACTIVITY

10.1. Reactivity:

Remark

10.2. Incompatibility with other substances:

None during normal operation. Avoid exposure to heat, open flames and corrosive substances.

10.3. Conditions to avoid:

Avoid exposure to heat and open flames. Do not puncture, crush or burn batteries.

11. TOXICOLOGICAL INFORMATION

This product does not exhibit toxicity when handled and used correctly. Signs and symptoms: None unless the battery is destroyed. Excessive exposure may cause symptoms of damage to non-fibrous lung tissue and irritation of the mucous membranes.
Inhalation: Lung irritation.
Skin contact: Skin irritation
Eye contact: Eye irritation
Ingestion: If swallowed, damage to the tissues of the larynx and gastrointestinal tract.
Medical conditions generally aggravated by exposure: Exposure to the internal contents of the battery may cause eczema, allergic skin reactions, lung damage, asthma and other respiratory diseases.

12. ECOLOGICAL INFORMATION

12.1. Toxicity

Aquatic toxicity:
No relevant information is available.
Persistence and degradability:
No relevant information is available. Behavior in ecological systems:
Bioaccumulative potential:
No relevant information is available.
Mobility in soil:
No relevant information is available.
Additional ecological information:
General information:
Do not allow spent battery cells to enter the soil.
They may corrode and leak electrolyte.
Results of PBT (persistent bioaccumulative toxic substance) and vPvB (very persistent bioaccumulative substance) assessment PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects:
No relevant information is available.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Dispose of batteries in accordance with national regulations or return spent batteries to the manufacturer.
Dispose of packaging in accordance with the instructions for disposal of packaging materials.
Wastewater disposal - current information Do not discharge into sewers.

13.2. Remarks

None

14. TRANSPORT INFORMATION

   
14.1. UN number UN 3481
14.2. UN proper shipping name Lithium ion batteries contained in equipment
14.3. Transport hazard class(es)
Class
Class 9
14.4. Packing group
14.5 Environmental hazards
not applicable
none (not hazardous to the environment in accordance with the Technical Regulations)

14.6 Special precautions for user

No additional information.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

The cargo is intended for transport in bulk.

14.8 Information for each of the UN Model Regulations

• Transport of dangerous goods by road, rail and inland waterways (ADR/RID/ADN)
Not subject to ADR, RID or ADN.
• International Maritime Dangerous Goods Code (IMDG)
Not subject to the IMDG Code.
• International Air Transport Association (ICAO-IATA/DGR)
Not subject to ICAO-IATA.

15. INFORMATION ON NATIONAL AND INTERNATIONAL LEGISLATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Relevant European Union (EU) provisions
• Regulation 649/2012/EC on the export and import of hazardous chemicals (PIC)
Not listed
• Regulation 1005/2009/EC on substances that deplete the ozone layer (ODS)
Not listed
• Regulation 850/2004/EC on persistent organic pollutants (POPs)
Not listed
• Restrictions under REACH, Annex XVII
Not listed
• List of substances subject to authorization (REACH, Annex XIV)
Not listed
• Directive 2011/65/EC on the restriction of the use of certain hazardous substances in electrical and electronic equipment (RoHS) - Annex II
Not listed
• Regulation 166/2006/EC establishing European Pollutant Release and Transfer Registers (PRTR)
Not listed
• Directive 2000/60/EC establishing a framework for Community action in the field of water policy (WFD)
Not listed
National regulations The substance is included in the following national regulations:

15.2 Chemical safety assessment

No chemical safety assessment has been carried out for this substance.

16. ADDITIONAL INFORMATION

Abbr. Abbreviations used
CAS Chemical Abstracts Service (a service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No. 1272/2008 on the classification, labeling and packaging of substances and mixtures
CMR Carcinogenic, mutagenic or toxic to the reproductive system
DGR Dangerous Goods Regulations (see IATA/DGR)
DMEL Derived minimal effect level
DNEL Derived minimal effect level
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European list of identified chemical substances
IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for air transport (IATA)
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of “Marine Pollutant)
NLP No-longer polymer
PBT Persistent, bioaccumulative and toxic
PNEC Predicted no-effect concentration
REACH Registration, Evaluation, Authorization and Restriction of Chemicals
vPvB Very persistent and very bioaccumulative
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Road on Inland Waterways)
ADR Accord européen relatif au transport international des marchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
ICAO International Civil Aviation Organization
IMDG International code for the transport of dangerous goods by sea
RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations concerning the International Carriage of Dangerous Goods by Rail)
GHS Globally Harmonized System of Classification and Labeling of Chemicals, developed by the United Nations

Key literature references and sources of data

Disclaimer

The information in this material safety data sheet reflects the current state of knowledge and applicable legislation. This material safety data sheet provides reference information on health, occupational safety and environmental protection during use of the product; it does not provide any guarantees regarding technical specifications or suitability for particular conditions of use.



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